IRSST - Institut de recherche Robert-Sauvé en santé et en sécurité du travail

Methylene chloride  

French name in the regulation: Chlorure de méthylène
CAS : 75-09-2
Synonyms: Dichlorométhane

Exposure Standards in RROHS regulation

Permissible exposure values (PEV)
ppm mg/m3 f/cc Notes
TWAEV 50 174 - -
STEV - - - -
Ceiling - - - -
Carcinogenicity C2 Sensitizer
Simple asphyxiantPercutaneous
Prohibited useProhibited recirculation
Minimum exposure Explosion hazard
Ototoxic

TWA adjustment for unusual work schedules

IV : Daily or weekly adjustment ( the more stringent of the two)

CNESST – Toxicological Index Service

Consult REPTOX file: Methylene chloride

Analysis:

Chlorure de méthylène

Method: IRSST - 27-2
Sampling device:
Sampling media required:
#IRSSTDescription
2120 Activated charcoal tube 100/50 mg

Parameters:
Flow rate: Max: 0,2 L/min
TWA sampling volume: 3 L
STEL sampling volume: -
Principle: Gas chromatography with flame ionization detection (GC-FID)
Precision (%): 4,7
Minimum reported value: 27 µg
Remarks: The analysis can be done by gas chromatography coupled with mass spectrometry (GC-MS, IRSST method #369); in this case the analytical uncertainty (CVa) is 5.6%.
IRSST. "Analyse du chlorure de méthylène dans l'air". Méthode 27-2. Méthodes analytiques. Montréal: IRSST, 1995.

Methylene chloride

Method: IRSST - 416
Sampling device:
Sampling media required:
#IRSSTDescription
2696 566AT passive dosimeter

Parameters:
Flow rate: 0,00954 L/min
TWA sampling volume: -
STEL sampling volume: -
Remarks: For the monitors, the flow must be considered as being a sampling rate.
Principle: Gas chromatography with flame ionization detection (GC-FID)
Precision (%): 7,6
Minimum reported value: 40 µg
IRSST. "Dosage des composés organiques volatils dans l'air par dosimétrie passive". Méthode 416. Non publiée.